The density at all points of a homogeneous object equals its total mass divided by its total volume. The oscillating U-tube densitometer method is a technique to determine the density of liquids and gases based on an electronic measurement of the frequency of oscillation, from which the density value is calculated. This measuring principle is based on the Mass-Spring Model.
The sample is filled into a container with oscillation capacity. The eigenfrequency of this container is influenced by the sample’s mass. This container with oscillation capacity is a hollow, U-shaped glass tube (oscillating U-tube) which is electronically excited into undamped oscillation (at the lowest possible amplitude). The two branches of the U-shaped oscillator function as its spring elements.
The direction of oscillation is normal to the level of the two branches. The oscillator’s eigenfrequency is only influenced by the part of the sample that is actually involved in the oscillation. The volume involved in the oscillation is limited by the stationary oscillation knots at the bearing points of the oscillator. If the oscillator is at least filled up to its bearing points, the same precisely defined volume always participates in the oscillation, thus the measured value of the sample’s mass can be used to calculate its density.
In the digital density meter, the mechanic oscillation of the U-tube is e.g. electromagnetically transformed into an alternating voltage of the same frequency. The period τ can be measured with high resolution and stands in simple relation to the density ρ of the sample in the oscillator:
ρ= A∙τ² - B
A and B are the respective instrument constants of each oscillator. Their values are determined by calibrating with two substances of the precisely known densities ρ1 and ρ2. Modern instruments calculate and store the constants A and B after the two calibration measurements, which are mostly performed with air and water. They employ suitable measures to compensate various parasitic influences on the measuring result, e.g. the influence of the sample’s viscosity and the non-linearity caused by the measuring instrument’s finite mass.
